Solvent quality and nonbiological oligomer folding: revisiting conventional paradigms

Author:

Dongmo Foumthuim Cedrix J.12ORCID,Arcangeli Tobia23,Škrbić Tatjana2ORCID,Giacometti Achille24ORCID

Affiliation:

1. INFN, Sezione di Roma Tor Vergata, Via della Ricerca Scientifica 1, 00133 Roma, Italy

2. Dipartimento di Scienze Molecolari e Nanosistemi, Università Ca’ Foscari Venezia, Via Torino 155, 30172 Venezia, Italy

3. Dipartimento di Chimica, Materiali e Ingegneria Chimica “Giulio Natta”, Politecnico di Milano, Sede Leonardo Edificio 6, Piazza Leonardo da Vinci 32, I-20133 Milano, Italy

4. European Centre for Living Technology (ECLT) Ca’ Bottacin, Dorsoduro 3911, Calle Crosera, 30123 Venice, Italy

Abstract

Solvation properties of poly-phenylacetylene synthetic foldamer (pPA) (left) and phenylalanile oligopeptide (PHE) (right), in three solvents. PHE is entropy–enthalpy compensating in water, pPA is displaying a large dominance of the enthalpic part.

Funder

Ministero dell’Istruzione, dell’Università e della Ricerca

Publisher

Royal Society of Chemistry (RSC)

Reference67 articles.

1. M.Doi and S. F.Edwards , The Theory of Polymer Dynamics (International Series of Monographs on Physics) , Clarendon Press , 1988

2. P.-G.De Gennes , Scaling concepts in polymer physics , Cornell University Press , 1979

3. A. R.Khokhlov , A. Y.Grosberg and V. S.Pande , Statistical Physics of Macromolecules (Polymers and Complex Materials) , American Institute of Physics , 1994th edn, 2002

4. M.Rubinstein and R. H.Colby , Polymer Physics (Chemistry) , Oxford University Press , 1st edn, 2003

5. Correlations among solvent polarity scales, dielectric constant and dipole moment, and a means to reliable predictions of polarity scale values from cu

同舟云学术

1.学者识别学者识别

2.学术分析学术分析

3.人才评估人才评估

"同舟云学术"是以全球学者为主线,采集、加工和组织学术论文而形成的新型学术文献查询和分析系统,可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容,当前同舟云学术共收录了国内外主流学术期刊6万余种,收集的期刊论文及会议论文总量共计约1.5亿篇,并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询!咨询电话:010-8811{复制后删除}0370

www.globalauthorid.com

TOP

Copyright © 2019-2024 北京同舟云网络信息技术有限公司
京公网安备11010802033243号  京ICP备18003416号-3