Synthesis of a rhodium(i) germyl complex: a useful tool for C–H and C–F bond activation reactions
Author:
Affiliation:
1. Humboldt-Universität zu Berlin
2. Department of Chemistry
3. D-12489 Berlin
4. Germany
Abstract
The rhodium(i) germyl complex [Rh(GePh3)(PEt3)3] is a useful tool for C–F and C–H bond activation reactions. For instance, treatment with hexafluoropropene results in the formation of two isomeric C–F activation products [Rh{(E)-CFCF(CF3)}(PEt3)3] and [Rh{(Z)-CFCF(CF3)}(PEt3)3] in a 3 : 1 ratio.
Funder
Deutsche Forschungsgemeinschaft
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2016/DT/C5DT04845A
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