An investigation of the interactions of Eu3+and Am3+with uranyl minerals: implications for the storage of spent nuclear fuel

Author:

Biswas Saptarshi12345,Steudtner Robin6789,Schmidt Moritz6789,McKenna Cora1011234,León Vintró Luis1213145,Twamley Brendan12345,Baker Robert J.12345

Affiliation:

1. School of Chemistry

2. University of Dublin

3. Trinity College

4. Dublin 2

5. Ireland

6. Helmholtz-Zentrum Dresden-Rossendorf e.V.

7. Institute of Resource Ecology

8. D-01314 Dresden

9. Germany

10. Department of Geology

11. School of Natural Sciences

12. School Of Physics

13. University College Dublin

14. Dublin 4

Abstract

Eu(iii) can incorporate into the structure of selected uranyl minerals, as shown emission and vibrational spectroscopy.241Am(iii) tracer studies have been conducted, which has implications for the migration of Am(iii) in an underground repository containing SNF.

Funder

Irish Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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