Semi-syntheses of the 11-hydroxyrotenoids sumatrol and villosinol-Reference-Cited by-同舟云学术

Semi-syntheses of the 11-hydroxyrotenoids sumatrol and villosinol

Published:2018 Issue:35 Volume:16 Page:6395-6398
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Russell David A.¹²³⁴^ORCID,Freudenreich Julien J.¹²³⁴,Stewart Hannah L.¹²³⁴,Bond Andrew D.¹²³⁴^ORCID,Sore Hannah F.¹²³⁴,Spring David R.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. University of Cambridge

3. Cambridge

4. UK

Abstract

We describe semi-syntheses of the 11-hydroxyrotenoids sumatrol (1) and villosinol (2), starting from rotenone (5), using an oxime-directed C₁₁–H functionalisation approach.

Funder

Wellcome Trust

Cancer Research UK

Royal Society

Medical Research Council

Biotechnology and Biological Sciences Research Council

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/OB/C8OB01919C

Reference36 articles.

1. The Physical society

2. 111. Sumatrol. Part I

3. 318. Experiments on the synthesis of rotenone and its derivatives. Part XIV. The structure of toxicarol

4. 106. The action of alkali on rotenone and related substances

5. 1072. Structure and stereochemistry of sumatrol and malaccol

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