Carbon-based SILP catalysis for the selective hydrogenation of aldehydes using a well-defined Fe(ii) PNP complex

Author:

Castro-Amoedo Rafael1234,Csendes Zita1234,Brünig Julian1234,Sauer Markus5234ORCID,Foelske-Schmitz Annette5234,Yigit Nevzat6234,Rupprechter Günther6234,Gupta Tushar6234,Martins Ana Margarida7891011ORCID,Bica Katharina1234ORCID,Hoffmann Helmuth1234,Kirchner Karl1234ORCID

Affiliation:

1. Institute of Applied Synthetic Chemistry

2. Vienna University of Technology

3. A-1060 Vienna

4. Austria

5. Analytical Instrumentation Center

6. Institute of Materials Chemistry

7. Centro de Química Estrutural

8. Instituto Superior Técnico

9. Universidade de Lisboa

10. 1049-001 Lisboa

11. Portugal

Abstract

In this work, the supported ionic liquid phase (SILP) method was applied for the immobilization of a newly developed, well-defined hydride Fe(ii) PNP pincer complex dissolved an in ionic liquid (IL) onto polymer-based spherical activated carbon.

Funder

Austrian Science Fund

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Reference92 articles.

1. Handbook of Homogeneous Hydrogenation , ed. J. G. de Vries and C. J. Elsevier , Wiley-VCH , Weinheim , 2007

2. P. Dupau , in Organometallics as Catalysts in the Fine Chemical Industry , ed. M. Beller and H. U. Blaser , Springer-Verlag , Berlin , 2012

3. Industrial-Scale Synthesis and Applications of Asymmetric Hydrogenation Catalysts

4. Catalytic Reductive Transformations of Carboxylic and Carbonic Acid Derivatives Using Molecular Hydrogen

5. Selective Hydrogenation for Fine Chemicals: Recent Trends and New Developments

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