syn-Bimane as a chelating O-donor ligand for palladium(ii)
Author:
Affiliation:
1. Department of Chemical Sciences
2. Ariel University
3. Ariel 40700
4. Israel
5. Department of Chemical Research Support
6. Weizmann Institute of Science
7. Rehovot 76100
8. Department of Chemical Engineering and Biotechnology
Abstract
The first example of a metal-coordinated bimane scaffold, a cationic Pd(ii)-syn-bimane complex, was prepared and characterized. Its crystal structure reveals a nonplanar bimane framework. Spectroscopic evidence shows that bimane coordination is reversible in solution.
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2016/DT/C6DT02141G
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