Unusual behaviour of the spin–spin coupling constant 1JCH upon formation of CH⋯X hydrogen bond

Author:

Tupikina Elena Yu.1234ORCID,Denisov Gleb S.5234,Antonov Alexander S.1234ORCID,Tolstoy Peter M.1234ORCID

Affiliation:

1. Institute of Chemistry

2. St. Petersburg State University

3. St. Petersburg 198504

4. Russia

5. Department of Physics

Abstract

One-bond coupling constants 1JXY are usually used as a measure of the corresponding X⋯Y interatomic distances.

Funder

Russian Foundation for Basic Research

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Reference31 articles.

1. The occurrence of CH…O hydrogen bonds in α-helices and helix termini in globular proteins

2. Can a C–H···O Interaction Be a Determinant of Conformation?

3. M. Nishio , Y.Umezawa , H.Suezawa and S.Tsuboyama , The CH/π hydrogen bond: implication in crystal engineering in The importance of pi-interactions in crystal engineering: frontiers in crystal engineering , ed. E. R. T. Tiekink and J. Zukerman-Schpector , Wiley , New York , 2012

4. Undirected, Homogeneous C–H Bond Functionalization: Challenges and Opportunities

5. Blue-Shifting Hydrogen Bonds

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