Triamidoamine-supported zirconium: hydrogen activation, Lewis acidity, and rac-lactide polymerization
Author:
Affiliation:
1. Department of Chemistry
2. University of Vermont
3. Burlington
4. USA
5. Department of Chemistry and Biochemistry
6. University of Lethbridge
7. Lethbridge
8. Canada T1K 3M4
9. Vassar College
10. Poughkeepsie
11. Boston College
12. Chestnut Hill
Abstract
Investigation of a triamidoamine-supported zirconium hydride intermediate, important to a range of catalytic reactions, revealed the potential Lewis acidity of [κ5-N,N,N,N,C-(Me3SiNCH2CH2)2NCH2CH2NSiMe2CH2]Zr (1).
Funder
Division of Chemistry
Canadian Network for Research and Innovation in Machining Technology, Natural Sciences and Engineering Research Council of Canada
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemical Engineering,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2016/RA/C6RA15617G
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4. Differences in the stability of zirconium(IV) complexes related to catalytic phosphine dehydrocoupling reactions
5. Triamidoamine-supported zirconium complexes in the catalytic dehydrocoupling of 1,2-bisphosphinobenzene and -ethane
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