Asymmetric sulfoxidation by engineering the heme pocket of a dye-decolorizing peroxidase-Reference-Cited by-同舟云学术

Asymmetric sulfoxidation by engineering the heme pocket of a dye-decolorizing peroxidase

Published:2016 Issue:16 Volume:6 Page:6277-6285
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Linde Dolores¹²³⁴,Cañellas Marina⁵⁶⁷⁴⁸,Coscolín Cristina¹²³⁴,Davó-Siguero Irene¹²³⁴,Romero Antonio¹²³⁴,Lucas Fátima⁵⁶⁷⁴⁸,Ruiz-Dueñas Francisco J.¹²³⁴,Guallar Victor⁵⁶⁷⁴⁹,Martínez Angel T.¹²³⁴

Affiliation:

1. Centro de Investigaciones Biológicas

2. CSIC

3. E-28040 Madrid

4. Spain

5. Joint BSC-CRG-IRB Research Program in Computational Biology

6. Barcelona Supercomputing Center

7. E-08034 Barcelona

8. Anaxomics Biotech

9. ICREA

Abstract

By enlarging the active site of DyP, F359G stereoselectively converting methyl-phenyl sulfide (MPS) into S methyl-phenyl sulfoxide (MPSO) was obtained, while the parent DyP has no activity, and L357G yields racemic mixtures.

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CY/C6CY00539J

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