Selective synthesis of cis- and trans-[(NHCMe)2PtCl2] and [NHCMePt(cod)Cl][NHCMePtCl3] using NHCMeSiCl4-Reference-Cited by-同舟云学术

Selective synthesis of cis- and trans-[(NHCMe)2PtCl2] and [NHCMePt(cod)Cl][NHCMePtCl3] using NHCMeSiCl4

Published:2014 Issue:42 Volume:43 Page:15700-15703
ISSN:1477-9226
Container-title:Dalton Trans.
language:en
Short-container-title:Dalton Trans.

Author:

Lewis-Alleyne Lesley C.¹²³⁴⁵,Bassil Bassem S.⁴⁵⁶,Böttcher Tobias⁷⁸⁹,Röschenthaler Gerd-Volker⁴⁵⁶

Affiliation:

1. School of Science and Technology

2. University of the Southern Caribbean

3. St. Joseph, Trinidad and Tobago

4. School of Engineering and Science

5. Jacobs University Bremen

6. 28759 Bremen, Germany

7. School of Chemistry

8. Monash University

9. Melbourne, Australia

Abstract

NHC^MeSiCl₄ was used to selectively synthesise cis and trans-[(NHC^Me)₂PtCl₂], as well as [NHC^MePt(cod)Cl][NHC^MePtCl₃], which revealed the first ever N-heterocyclic carbene analogue of the Cossa's salt anion.

Funder

German Academic Exchange Service

Alexander von Humboldt-Stiftung

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/DT/C4DT02214A

Reference34 articles.

1. N-Heterocyclic Carbenes

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5. Current Status of Platinum-Based Antitumor Drugs

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