Synthesis of Hofmann-based metal–organic frameworks incorporating a bis-pyrazole linker for various gas separations-Reference-Cited by-同舟云学术

Synthesis of Hofmann-based metal–organic frameworks incorporating a bis-pyrazole linker for various gas separations

Published:2024 Issue:25 Volume:12 Page:15106-15114
ISSN:2050-7488
Container-title:Journal of Materials Chemistry A
language:en
Short-container-title:J. Mater. Chem. A

Author:

Matthews Brooke L.¹²,Harvey-Reid Nathan C.¹²^ORCID,Jangodaz Elnaz²³,Scott Victoria-Jayne²³,Polson Matthew I. J.¹^ORCID,Maibam Ashakiran⁴⁵⁶,Babarao Ravichandar⁴⁷⁸^ORCID,Telfer Shane G.²³^ORCID,Kruger Paul E.¹²^ORCID

Affiliation:

1. School of Physical and Chemical Sciences, University of Canterbury, Christchurch 8140, New Zealand

2. MacDiarmid Institute for Advanced Materials and Nanotechnology, New Zealand

3. School of Natural Sciences, Massey University, Palmerston North 4410, New Zealand

4. School of Science, Centre for Advanced Materials, Industrial Chemistry (CAMIC), RMIT University, Melbourne, VIC, 3001, Australia

5. Physical and Materials Division, CSIR-National Chemical Laboratory, Pune 411008, India

6. Academy of Scientific and Innovative Research (AcSIR), Ghaziabad 201002, India

7. CSIRO Future Industries-Manufacturing Business Unit, Clayton, VIC, 3169, Australia

8. ARC Centre of Excellence for Green Electrochemical Transformation of Carbon Dioxide, School of Science, RMIT University, Melbourne, VIC, 3000, Australia

Abstract

We report the synthesis of two novel Hofmann-type metal–organic frameworks, [Co(H2mdp)(Ni(CN)4)] and [Fe(H2mdp)(Ni(CN)4)], using a pyrazole based organic linker. Both materials show good selectivity for C2H2 and C3H6 for several gas separations.

Funder

MacDiarmid Institute for Advanced Materials and Nanotechnology

National Computational Infrastructure

University of Canterbury

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/TA/D4TA00507D

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