Effect of the substituent on C–H activation catalyzed by a non-heme Fe(<scp>iv</scp>)O complex: a computational investigation of reactivity and hydrogen tunneling-Reference-Cited by-同舟云学术

Effect of the substituent on C–H activation catalyzed by a non-heme Fe(iv)O complex: a computational investigation of reactivity and hydrogen tunneling

Published:2022 Issue:31 Volume:51 Page:11641-11649
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Katoch Akanksha¹,Mandal Debasish¹^ORCID

Affiliation:

1. School of Chemistry and Biochemistry, Thapar Institute of Engineering and Technology, Patiala-147001, Punjab, India

Abstract

Electron-donating substituent on the metal enhances the C–H activation reactivity due to the consequence of quantum mechanical tunneling, which increases with the anti-electrophilicity of the central metal.

Funder

Ministry of Education, India

Thapar Institute of Engineering and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D2DT01529C

Reference67 articles.

1. Non-Heme Fe(IV)–Oxo Intermediates

2. The Road to Non-Heme Oxoferryls and Beyond