Synthesis and structural characterization of stable coinage metal (Cu, Ag, Au) cyclopentadienyl complexes-Reference-Cited by-同舟云学术

Synthesis and structural characterization of stable coinage metal (Cu, Ag, Au) cyclopentadienyl complexes

Published:2024 Issue:8 Volume:15 Page:2990-2995
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Sievers Robin¹,Reimann Marc²^ORCID,Kub Nico G.¹,Rupf Susanne M.¹^ORCID,Kaupp Martin²^ORCID,Malischewski Moritz¹^ORCID

Affiliation:

1. Freie Universität Berlin, Fabeckstraße 34/36, 14195 Berlin, Germany

2. Technische Universität Berlin, Straße des 17. Juni 135, 10623 Berlin, Germany

Abstract

We report the first complete series of structurally characterized cyclopentadienyl complexes of coinage metals. Their unusually high stability is due to the high oxidative stability of the perfluorinated Cp* ligand [C5(CF3)5]−.

Funder

Deutsche Forschungsgemeinschaft

Fonds der Chemischen Industrie

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D3SC06299F

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