“Armed and disarmed” theory in the addition of an azide radical to glucals-Reference-Cited by-同舟云学术

“Armed and disarmed” theory in the addition of an azide radical to glucals

Published:2015 Issue:48 Volume:5 Page:38577-38580
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Wang Wenjun¹²³⁴⁵,Yang Zhongyue⁶⁴⁷⁸,Xu Yun¹²³⁴⁵,Liu Taibao¹²³⁴⁵,Song Tianbang¹²³⁴⁵,Zhao Yunyan¹²³⁴⁵,Xu Xiufang⁶⁴⁷⁸,Zhao Wei¹²³⁴⁵,Wang Peng George¹²³⁴⁵

Affiliation:

1. College of Pharmacy

2. State Key Laboratory of Elemento-organic Chemistry

3. Tianjin Key Laboratory of Molecular Drug Research and Synergetic Innovation Center of Chemical Science and Engineering

4. Nankai University

5. Tianjin 300071

6. College of Chemistry

7. Tianjin

8. PR China

Abstract

“Armed” glucals were prone to undergo kinetic process. The torsional strains govern the selectivity. Meanwhile, “disarmed” glucals preferred thermodynamic radical addition. A sialic acid containing trisaccharide was also synthesized by the method.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/RA/C5RA00296F

Reference29 articles.

1. Fluorinated Glycosyl Amino Acids for Mucin-Like Glycopeptide Antigen Analogues

2. Highly efficient preparation of tumor antigen-containing glycopeptide building blocks from novel pentenyl glycosides

3. Solution and solid-state structure of N-acetamido-3,4,6-tri-O-acetyl-2-azido-2-deoxy-α-d-galactopyranosylamine

4. Synthèse d'oligomères du polysaccharide capsulaire de Salmonella typhi, bactérie à l'origine de la fièvre typhoïde

5. Solution-Phase Synthesis with Solid-State Workup of an O-Glycopeptide with a Cluster of Cancer-Related T Antigens

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