Molecular signature of polyoxometalates in electron transport of silicon-based molecular junctions
Author:
Affiliation:
1. Sorbonne Université
2. CNRS
3. Institut Parisien de Chimie Moléculaire
4. IPCM
5. F-75005 Paris
6. Institute for Electronics Microelectronics and Nanotechnology (IEMN)
7. F-59652 Villeneuve d'Ascq
8. France
Abstract
The tunnel energy barriers of two polyoxometalate-based molecular junctions were found to depend on the nature of the metal W/Mo.
Publisher
Royal Society of Chemistry (RSC)
Subject
General Materials Science
Link
http://pubs.rsc.org/en/content/articlepdf/2018/NR/C8NR04946G
Reference100 articles.
1. M. T. Pope , Heteropoly and Isopoly Oxometalates , Springler , New-York , 1983
2. Electrochemical Properties of Polyoxometalates as Electrocatalysts
3. Electronic and Magnetic Properties of α-Keggin Anions: A DFT Study of [XM12O40]n-, (M = W, Mo; X = AlIII, SiIV, PV, FeIII, CoII, CoIII ) and [SiM11VO40]m- (M = Mo and W)
4. Ab initio and DFT modelling of complex materials: towards the understanding of electronic and magnetic properties of polyoxometalates
5. M. T. Pope , in Polyoxometalate Molecular Science , ed. J. J. Borras-Almenar , E. Coronado , A. Müller and M. T. Pope , Kluwer Academic Publishers , Dortrecht , 2003 , pp. 3–31
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