Highly efficient palladium-catalysed carbon dioxide hydrosilylation employing PMP ligands-Reference-Cited by-同舟云学术

Highly efficient palladium-catalysed carbon dioxide hydrosilylation employing PMP ligands

Published:2019 Issue:3 Volume:48 Page:1017-1022
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Steinhoff Patrick¹²³⁴,Paul Melanie¹²³⁴,Schroers Julian P.¹²³⁴,Tauchert Michael E.¹²³⁴^ORCID

Affiliation:

1. Institute of Inorganic Chemistry

2. RWTH Aachen University

3. D-52074 Aachen

4. Germany

Abstract

A series of zero-valent Pd complexes featuring PMP ligands (M = Li^I, Cu^I, Zn^II) is reported. An excellent activity in chemoselective CO₂ hydrosilylation producing silyl formate is observed (TOF_1/2 = 3000 h⁻¹).

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C8DT03777A

Reference52 articles.

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