Two rare-earth-based quaternary chalcogenides EuCdGeQ4 (Q = S, Se) with strong second-harmonic generation

Author:

Xing Wenhao12345,Wang Naizheng56789ORCID,Guo Yangwu56789,Li Zhuang56789,Tang Jian123410,Kang Kaijin123410,Yin Wenlong123411ORCID,Lin Zheshuai56789,Yao Jiyong56789ORCID,Kang Bin123411

Affiliation:

1. Institute of Chemical Materials

2. China Academy of Engineering Physics

3. Mianyang 621900

4. People's Republic of China

5. Center for Crystal Research and Development

6. Key Laboratory of Functional Crystals and Laser Technology

7. Technical Institute of Physics and Chemistry

8. Chinese Academy of Sciences

9. Beijing 100190

10. Physics and Space Science College

11. Key Laboratory of Science and Technology on High Energy Laser

Abstract

Two RE-based quaternary metal chalcogenides EuCdGeQ4 (Q = S, Se) are discovered. They possess many attractive properties as preferred IR NLO materials including large band gaps, phase-matched intense SHG and congruent melting behavior.

Funder

China Academy of Engineering Physics

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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