Synthesis, photophysical and electrochemical properties of chiral and achiral thiadiazolophanes-Reference-Cited by-同舟云学术

Synthesis, photophysical and electrochemical properties of chiral and achiral thiadiazolophanes

Published:2014 Issue:45 Volume:4 Page:23433-23439
ISSN:2046-2069
Container-title:RSC Adv.
language:en
Short-container-title:RSC Adv.

Author:

Thirunarayanan Ayyavu¹²³⁴,Rajakumar Perumal¹²³⁴

Affiliation:

1. Department of Organic Chemistry

2. University of Madras

3. Guindy Campus

4. Chennai 600 025, India

Abstract

One pot synthesis of chiral and achiral 2:2 oligomeric thiadiazolophane 1 and 3 and 3:3 oligomeric thiadiazolophane 2 and 4 with (S)-BINOL and methylene bis-naphthyl spacer unit has been achieved. The photophysical and electrochemical properties revealed higher degree of aggregation in 2:2 oligomor than 3:3 oligomer. Energy minimized calculations show that 3:3 oligomer has less heat of formation than 2:2 oligomer.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/RA/C4RA02672A

Reference66 articles.

1. Electroactive polymer sensors for chiral amines based on optically active 1,1′-binaphthyls

2. Supramolecular complexation for environmental control

3. Synthesis of a new bisbinaphthyl macrocycle for enantioselective fluorescent recognition

4. Crown Ethers: Sensors for Ions and Molecular Scaffolds for Materials and Biological Models

5. Redox Switchable Ionophores for Heavy and Transition Metal Cations

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