A one-pot route to N-acyl ureas: a formal four-component hydrolytic reaction involving aminonitrones and isocyanide dibromides
Author:
Affiliation:
1. Institute of Chemistry
2. Saint Petersburg State University
3. Saint Petersburg
4. Russian Federation
5. Center for X-ray Diffraction Studies
Abstract
A one-pot route to N-acyl ureas proceeds via generation of electrophilically activated 2-substituted 1,2,4-oxadiazolium salts. The conformation of the N-acyl ureas is stabilized via moderate strength (6.2–7.8 kcal mol−1) resonance-assisted hydrogen bonds.
Funder
Russian Foundation for Basic Research
Russian Science Foundation
Publisher
Royal Society of Chemistry (RSC)
Subject
Materials Chemistry,General Chemistry,Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2020/NJ/C9NJ05445F
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5. Two-Dimensional Aggregation of Organogelators Induced by Biaxial Hydrogen-Bonding Gives Supramolecular Nanosheets
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