Terminal group engineering for small-molecule donors boosts the performance of nonfullerene organic solar cells

Author:

Duan Tainan1234ORCID,Tang Hua12345,Liang Ru-Ze56789,Lv Jie1234,Kan Zhipeng12345ORCID,Singh Ranbir10111213,Kumar Manish14151613ORCID,Xiao Zeyun1234,Lu Shirong1234ORCID,Laquai Frédéric56789ORCID

Affiliation:

1. Chongqing Institute of Green and Intelligent Technology

2. Chinese Academy of Sciences

3. Chongqing

4. China

5. Physical Science and Engineering Division

6. KAUST Solar Center (KSC)

7. King Abdullah University of Science and Technology (KAUST)

8. Thuwal 23955-6900

9. Saudi Arabia

10. Department of Energy and Materials Engineering

11. Dongguk University

12. Seoul

13. Korea

14. Pohang Accelerator Laboratory

15. Pohang University of Science and Technology

16. Pohang

Abstract

Two new small molecule donors (BDT-RO and BDT-RN) with esterified rhodanine (RE) as the terminal group are designed and synthesized. By combining with the fused-ring acceptor IDIC, a high PCE of over 9.0% is achieved by BDT-RO, and its isomer BDT-RN also shows a PCE close to 8.4%.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Chongqing

Recruitment Program of Global Experts

King Abdullah University of Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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