Spin-labelled mechanically interlocked molecules as models for the interpretation of biradical EPR spectra-Reference-Cited by-同舟云学术

Spin-labelled mechanically interlocked molecules as models for the interpretation of biradical EPR spectra

Published:2021 Issue: Volume: Page:
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Gualandi Lorenzo¹²³⁴,Franchi Paola¹²³⁴,Mezzina Elisabetta¹²³⁴,Goldup Stephen M.⁵⁶⁷⁸^ORCID,Lucarini Marco¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry “Giacomo Ciamician”

2. University of Bologna

3. Bologna

4. Italy

5. Department of Chemistry

6. University of Southampton

7. Southampton

8. UK

Abstract

Using a rotaxane biradical, we unambiguously demonstrate the need consider both J and rate of conformational interconversion carefully when interpreting the spectra of such systems when they are employed as spin probes in solution.

Funder

European Research Council

Ministero dell'Istruzione, dell'Università e della Ricerca

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/SC/D1SC01462E

Reference119 articles.

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4. Chemical consequences of mechanical bonding in catenanes and rotaxanes: isomerism, modification, catalysis and molecular machines for synthesis

5. Rotaxane-Stabilized Thiophosphonium Salt from Disulfide and Phosphine

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