Metal cation substitution can tune CO2, H2O and CH4 switching pressure in transiently porous coordination networks

Author:

Nikolayenko Varvara I.1ORCID,Castell Dominic C.1ORCID,Sensharma Debobroto1ORCID,Shivanna Mohana2,Loots Leigh3ORCID,Otake Ken-ichi2ORCID,Kitagawa Susumu2,Barbour Leonard J.3ORCID,Zaworotko Michael J.1ORCID

Affiliation:

1. Department of Chemical Sciences, Bernal Institute, University of Limerick, Limerick V94T9PX, Republic of Ireland

2. Institute for Integrated Cell-Material Sciences (iCeMS), Institute for Advanced Study, Kyoto University (KUIAS), Yoshida Ushinomiyacho, Sakyoku, Kyoto 606-8501, Japan

3. Department of Chemistry and Polymer Science, University of Stellenbosch, Matieland 7600, South Africa

Abstract

[X-dmp-1-M] (M = Co, Zn and Cd), a family of transiently porous coordination networks, exhibits varied switching behaviour for H20, CO2 and CH4 enabled by metal cation substitution.

Funder

Science Foundation Ireland

Irish Research Council

Japan Society for the Promotion of Science

H2020 European Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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