Light harvesting indolyl-substituted phosphoramide ligand for the enhancement of Mn(ii) luminescence

Author:

Bortoluzzi Marco12345ORCID,Castro Jesús678910ORCID,Gobbo Alberto1112134ORCID,Ferraro Valentina1234ORCID,Pietrobon Luca1234

Affiliation:

1. Dipartimento di Scienze Molecolari e Nanosistemi

2. Università Ca’ Foscari Venezia

3. 30170 Mestre (VE)

4. Italy

5. Consorzio Interuniversitario Reattività Chimica e Catalisi (CIRCC)

6. Departamento de Química Inorgánica

7. Universidade de Vigo

8. Facultade de Química

9. Edificio de Ciencias Experimentais

10. 36310 Vigo

11. Dipartimento di Chimica e Chimica Industriale

12. Università di Pisa

13. 56124 Pisa

Abstract

Excitation of the coordinated ligands in tetrahedral complexes having the general formula [MnX2L2] (X = Cl, Br, I; L = N,N′,N′-tetramethyl-P-indol-1-ylphosphonic diamide) causes bright green luminescence from the Mn(ii) centre.

Funder

Università Ca' Foscari di Venezia

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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