The rich structural phase behaviour of 2,2,2-trifluoroethanol-Reference-Cited by-同舟云学术

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The rich structural phase behaviour of 2,2,2-trifluoroethanol

Published:2023 Issue:45 Volume:25 Page:6291-6302
ISSN:1466-8033
Container-title:CrystEngComm
language:en
Short-container-title:CrystEngComm

Author:

Barnett S. A.¹^ORCID,Bull C. L.²³^ORCID,Funnell N. P.²^ORCID,Allan D. R.¹^ORCID

Affiliation:

1. Diamond Light Source, Harwell Science and Innovation Campus, Didcot, Oxfordshire, OX11 0DE, UK

2. Rutherford Appleton Laboratory, ISIS Neutron and Muon Source, Didcot, Oxfordshire, OX11 0QX, UK

3. School of Chemistry, University of Edinburgh, David Brewster Road, Edinburgh, EH9 3FJ, UK

Abstract

A remarkable degree of polymorphism is exhibited in the high-pressure and low-temperature crystal structures of 2,2,2-trifluoroethanol, with the observation of four ordered phases (forms 1–4) and a cubic rotor phase (form 5).

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CE/D3CE00737E

Reference33 articles.

1. Anomalous Space-Group Frequencies for Monoalcohols CnHmOH

2. Rules governing the crystal packing of mono- and dialcohols

3. The low-temperature and high-pressure crystal structures of cyclobutanol (C4H7OH)

4. Realizing Predicted Crystal Structures at Extreme Conditions: The Low-Temperature and High-Pressure Crystal Structures of 2-Chlorophenol and 4-Fluorophenol

5. Pressure-induced polymorphism in phenol

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