Self-assembly of iodoacetylenyl-substituted nitronyl nitroxides via halogen bonding

Author:

Shurikov Matvey K.1ORCID,Tretyakov Evgeny V.2ORCID,Petunin Pavel V.1ORCID,Votkina Darya E.1ORCID,Romanenko Galina V.3ORCID,Bogomyakov Artem S.3ORCID,Burguera Sergi4ORCID,Frontera Antonio4ORCID,Kukushkin Vadim Yu.5ORCID,Postnikov Pavel S.1ORCID

Affiliation:

1. Research School of Chemistry & Applied Biomedical Sciences, Tomsk Polytechnic University, Lenin Av. 30, Tomsk 634050, Russian Federation

2. N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Leninsky Av. 47, Moscow 119991, Russian Federation

3. International Tomography Center, Siberian Branch of Russian Academy of Sciences, Institutskaya Str. 3a, Novosibirsk 630090, Russian Federation

4. Departament de Química, Universitat de les Illes Balears, Crta de Valldemossa km 7.5, 07122 Palma de Mallorca, Baleares, Spain

5. Institute of Chemistry, Saint Petersburg State University, Universitetskaya Nab. 7/9, Saint Petersburg 199034, Russian Federation

Abstract

Novel nitronyl nitroxides are assembled in the solid state into chains, in which the radical building blocks are linked by intermolecular I⋯N–O halogen bonding. Magnetic analyses revealed that in the nitroxides, the radicals are weakly coupled.

Funder

Ministry of Science and Higher Education of the Russian Federation

Russian Science Foundation

Ministerio de Ciencia e Innovación

Alexander von Humboldt-Stiftung

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

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