Alkali metal and stoichiometric effects in intermolecular hydroamination catalysed by lithium, sodium and potassium magnesiates-Reference-Cited by-同舟云学术

Alkali metal and stoichiometric effects in intermolecular hydroamination catalysed by lithium, sodium and potassium magnesiates

Published:2019 Issue:23 Volume:48 Page:8122-8130
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Davin Laia¹²³⁴⁵,Hernán-Gómez Alberto¹²³⁴⁵,McLaughlin Calum¹²³⁴⁵,Kennedy Alan R.¹²³⁴⁵^ORCID,McLellan Ross¹²³⁴⁵^ORCID,Hevia Eva¹²³⁴⁵^ORCID

Affiliation:

1. WestCHEM

2. Department of Pure and Applied Chemistry

3. University of Strathclyde

4. Glasgow

5. UK

Abstract

Cooperative catalytic hydroamination of diphenylacetylene and styrene is accomplished by magnesiates with efficiency dependent on the alkali metal and monoanionic or dianionic nature of the ate with dianionic [(PMDETA)₂K₂Mg(CH₂SiMe₃)₄] performing best.

Funder

H2020 European Research Council

Carnegie Trust for the Universities of Scotland

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT00923J

Reference58 articles.

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2. A. L. Reznichenko and K. C.Hultzsch , in Top Organomet Chem , ed. V. P. Ananikov and M. Tanaka , Springer Berlin Heidelberg , 2013 , pp. 51–114