Alkali metal and stoichiometric effects in intermolecular hydroamination catalysed by lithium, sodium and potassium magnesiates

Author:

Davin Laia12345,Hernán-Gómez Alberto12345,McLaughlin Calum12345,Kennedy Alan R.12345ORCID,McLellan Ross12345ORCID,Hevia Eva12345ORCID

Affiliation:

1. WestCHEM

2. Department of Pure and Applied Chemistry

3. University of Strathclyde

4. Glasgow

5. UK

Abstract

Cooperative catalytic hydroamination of diphenylacetylene and styrene is accomplished by magnesiates with efficiency dependent on the alkali metal and monoanionic or dianionic nature of the ate with dianionic [(PMDETA)2K2Mg(CH2SiMe3)4] performing best.

Funder

H2020 European Research Council

Carnegie Trust for the Universities of Scotland

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference58 articles.

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