Optical property trends in a family of {Mo6I8} aquahydroxo complexes

Author:

Marchuk Margarita V.123,Vorotnikova Natalya A.123,Vorotnikov Yuri A.123ORCID,Kuratieva Natalia V.123,Stass Dmitri V.45362,Shestopalov Michael A.123ORCID

Affiliation:

1. Nikolaev Institute of Inorganic Chemistry SB RAS

2. 630090 Novosibirsk

3. Russian Federation

4. Voevodsky Institute of Chemical Kinetics and Combustion SB RAS

5. Novosibirsk

6. Novosibirsk State University

Abstract

While investigating molybdenum clusters belonging to the family of aquahydroxo complexes, the four-component nature of the emission was demonstrated with both apical ligand type and structure density strongly affecting only the first two high energy components.

Funder

Russian Foundation for Basic Research

Russian Science Foundation

Ministry of Education and Science of the Russian Federation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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