A theoretical study of the addition of CH2OO to hydroxymethyl hydroperoxide and its implications on SO3 formation in the atmosphere-Reference-Cited by-同舟云学术

A theoretical study of the addition of CH2OO to hydroxymethyl hydroperoxide and its implications on SO3 formation in the atmosphere

Published:2020 Issue:25 Volume:22 Page:14130-14141
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Chow Ronald¹²³⁴,Mok Daniel K. W.¹²³⁴^ORCID

Affiliation:

1. Department of Applied Biology and Chemical Technology

2. Hong Kong Polytechnic University

3. Hung Hom

4. Hong Kong

Abstract

The reaction of hydroxymethyl hydroperoxide with the simplest Criegee intermediate has been examined using quantum chemical methods with transition state theory. Results suggested that the reaction could be an indirect source of H₂SO₄ in atmosphere.

Funder

Research Grants Council, University Grants Committee

Hong Kong Polytechnic University

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CP/D0CP00961J

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1. Convective injection and photochemical decay of peroxides in the tropical upper troposphere: Methyl iodide as a tracer of marine convection

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3. Observed OH and HO2in the upper troposphere suggest a major source from convective injection of peroxides

4. Experimental evidence for the importance of convected methylhydroperoxide as a source of hydrogen oxide (HOx) radicals in the tropical upper troposphere

5. Aqueous phase oxidation of sulfur(IV) by hydrogen peroxide, methylhydroperoxide, and peroxyacetic acid

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