Negatively charged platinum nanoparticles on dititanium oxide electride for ultra-durable electrocatalytic oxygen reduction

Author:

Hua Erbing1ORCID,Choi Seunggun2,Ren Siyuan1,Kim Sungjun3ORCID,Ali Ghulam4ORCID,Kim Seon Je1,Jang Woo-Sung1ORCID,Joo Soyun5ORCID,Zhang Jingshu5,Ji Seulgi6,Cho Yun Seong7,Kang Joohoon7ORCID,Song Taeseup2ORCID,Hong Seungbum5ORCID,Choi Heechae68ORCID,Kim Young-Min1ORCID,Han Hyuksu9ORCID,Kim Sung Wng1ORCID

Affiliation:

1. Department of Energy Science, Sungkyunkwan University, Suwon 16419, Republic of Korea

2. Department of Energy Engineering, Hanyang University, Seoul 04763, Republic of Korea

3. Hydrogen Energy Research Center, Korea Research Institute of Chemical Technology, Daejeon, Republic of Korea

4. U.S.-Pakistan Center for Advanced Studies in Energy (USPCASE), National University of Sciences and Technology (NUST), Sector H-12, Islamabad, Pakistan

5. Department of Materials Science and Engineering, KAIST, Daejeon, Republic of Korea

6. Institute of Inorganic Chemistry, University of Cologne, Greinstr. 6, 50939, Cologne, Germany

7. School of Advanced Materials Science and Engineering, Sungkyunkwan University, Suwon 16419, Republic of Korea

8. Department of Chemistry, Xi’an Jiaotong-Liverpool University, Suzhou, Jiangsu, 215123, China

9. Department of Energy Engineering, Konkuk University, Seoul 05029, Republic of Korea

Abstract

Negatively charged Pt nanoparticles supported by a [Ti2O]2+·2e electride with a self-passivation a-TiOx layer demonstrated superb long-term durability in the electrocatalytic ORR, which is superior to that of commercial Pt/C catalysts.

Funder

National Research Foundation of Korea

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Nuclear Energy and Engineering,Renewable Energy, Sustainability and the Environment,Environmental Chemistry

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