Two new hexanuclear titanium oxo cluster types and their structural connection to known clusters-Reference-Cited by-同舟云学术

Two new hexanuclear titanium oxo cluster types and their structural connection to known clusters

Published:2018 Issue:14 Volume:42 Page:12098-12103
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Czakler Matthias¹²³⁴,Artner Christine¹²³⁴,Schubert Ulrich¹²³⁴^ORCID

Affiliation:

1. Institute of Materials Chemistry

2. Technische Universität Wien

3. 1060 Wien

4. Austria

Abstract

Ti₆O₆(OiPr)₂(OOCR′)₁₀ (R′ = C₄H₇, Et) and Ti₆O₃(OiPr)₁₄(OOC–CHCH–COO)₂ represent new structure types of carboxylate-substituted clusters with a Ti₆O_x core (x = 3–6).

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2018/NJ/C8NJ01077C

Reference37 articles.

1. Chemical modification of titanium alkoxides for sol–gel processing

2. Titanium oxo-clusters: precursors for a Lego-like construction of nanostructured hybrid materials

3. Synthesis and characterization of new titanium hexanuclear oxo carboxylato alkoxides. Molecular structure of [Ti6(μ3-O)6(μ-O2CC6H4OPh)6(OEt)6]

4. Formic Acid Modified Ti(OCHMe2)4. Syntheses, Characterization, and X-ray Structures of Ti4(μ4-O)(μ-O)(OFc)2(μ-OR)4(OR)6 and Ti6(μ3-O)6(OFc)6(OR)6 (OFc = O2CH; OR = OCHMe2)

5. Implications for the Thin-Film Densification of TiO2 from Carboxylic Acid-Modified Titanium Alkoxides. Syntheses, Characterizations, X-ray Structures of Ti3(μ3-O)(O2CH)2(ONep)8, Ti3(μ3-O)(O2CMe)2(ONep)8, Ti6(μ3-O)6(O2CCHMe2)6(ONep)6, [Ti(μ-O2CCMe3)(ONep)3]2, and Ti3(μ3-O)(O2CCH2CMe3)2(ONep)8 (ONep = OCH2CMe3)1

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