Synthesis, structures, electrochemical and quantum chemical investigations of Ni(ii) and Cu(ii) complexes with a tetradentate Schiff base derived from 1-(2-thienyl)-1,3-butanedione

Author:

Ahumada Guillermo12345ORCID,Oyarce Jocelyn12345,Roisnel Thierry678910,Kahlal Samia678910,del Valle María Angélica11121314,Carrillo David12345,Saillard Jean-Yves678910,Hamon Jean-René678910ORCID,Manzur Carolina12345

Affiliation:

1. Laboratorio de Química Inorgánica

2. Instituto de Química

3. Facultad de Ciencias

4. Pontificia Universidad Católica de Valparaíso

5. Valparaíso

6. Univ Rennes

7. CNRS

8. ISCR (Institut des Sciences Chimiques de Rennes) – UMR 6226

9. F-35000 Rennes

10. France

11. Laboratorio de Electroquímica de Polímeros (LEP)

12. Pontificia Universidad Católica de Chile

13. 7820436 Macul

14. Chile

Abstract

Electrochemical oxidation of four-coordinate square planar Schiff-base Ni(ii) and Cu(ii) complexes leads to the formation of oligomers at the electrode.

Funder

Fondo Nacional de Desarrollo Científico y Tecnológico

Pontificia Universidad Católica de Valparaíso

Centre National de la Recherche Scientifique

Université de Rennes 1

Comisión Nacional de Investigación Científica y Tecnológica

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Reference39 articles.

1. R. Hernandez-Molina and A.Mederos , Acyclic and Macrocyclic Schiff Base Ligands , Comprehensive Coordination Chemistry II, ed. J. A. McCleverty and T. J. Meyer , Elsevier Pergamon , Oxford , 2004 , vol. 1, pp. 411–458

2. Advances in acyclic compartmental ligands and related complexes

3. Multidentate unsymmetrically-substituted Schiff bases and their metal complexes: Synthesis, functional materials properties, and applications to catalysis

4. Metal–Salen Schiff base complexes in catalysis: practical aspects

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