Deprotonated meso-hydroxyporphyrin as a stable π-electronic anion: the building unit of an ion-pairing assembly
Author:
Affiliation:
1. Department of Applied Chemistry
2. College of Life Sciences
3. Ritsumeikan University
4. Kusatsu 525-8577
5. Japan
6. Research and Utilization Division
7. Japan Synchrotron Radiation Research Institute
8. Sayo 679-5198
Abstract
The NiII complex of 5-hydroxy-10,15,20-tris(pentafluorophenyl)porphyrin was synthesized as a precursor of a negatively charged π-electronic system. Deprotonation provided an anionic species as the building unit of an ion-pairing assembly in combination with an aliphatic cation.
Funder
Japan Society for the Promotion of Science
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT01635B
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