The first ReI organometallic complex with an organoimido-polyoxometalate ligand

Author:

Hermosilla-Ibáñez Patricio12345,Wrighton-Araneda Kerry12345,Prado Gaspar67845,Paredes-García Verónica910567,Pizarro Nancy67845,Vega Andrés910567ORCID,Venegas-Yazigi Diego12345ORCID

Affiliation:

1. Universidad de Santiago de Chile

2. Facultad de Química y Biología

3. Departamento de Química de los Materiales

4. (IPMag)

5. Chile

6. Universidad Andres Bello

7. Facultad de Ciencias Exactas

8. Departamento de Ciencias Químicas

9. Centro para el Desarrollo de la Nanociencia y la Nanotecnología

10. CEDENNA

Abstract

An electrochemical, spectroscopic and theoretical study of the first ReI complex with a hybrid organoimido-polyoxometalate ligand is presented.

Funder

Comisión Nacional de Investigación Científica y Tecnológica

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference74 articles.

1. M. T. Pope , Polyoxo anions: synthesis and structure, in Comprehensive Coordination Chemistry II: Transition Metal Groups 3–6, ed. A. G. Wedd, Elsevier Science, New York, NY, USA, 2004, ch. 4.10, vol. 4

2. D. M. P. Mingos , Bonding and Charge Distribution in Poly-oxometalates: A Bond Valence Approach, Springer, 1999

3. C. L. Hill , Polyoxometalates: Reactivity, in Comprehensive Coordination Chemistry II: Transition Metal Groups 3–6, ed. A. G. Wedd, Elsevier Science, New York, NY, USA, 2004, ch 4.11, vol. 4

4. Polyoxometalates:  Very Large ClustersNanoscale Magnets

5. Magnetic polyoxometalates: from molecular magnetism to molecular spintronics and quantum computing

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