Dearomative 1,6-addition of P(O)–H to in situ formed p-QM-like ion pairs from 2-benzofuryl-ols to C3-phosphinoyl hydrobenzofurans-Reference-Cited by-同舟云学术

Dearomative 1,6-addition of P(O)–H to in situ formed p-QM-like ion pairs from 2-benzofuryl-ols to C3-phosphinoyl hydrobenzofurans

Published:2021 Issue:8 Volume:8 Page:1756-1763
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Chen Long¹²³⁴⁵^ORCID,Zou Yun-Xiang¹²³⁴⁵,Zheng Shi-Lu¹²³⁴⁵,Liu Xiao-Yan¹²³⁴⁵,Yang Hong-Li¹²³⁴⁵,Zhang Jing¹²³⁴⁵,Zeng Yao¹²³⁴⁵,Duan Li¹²³⁴⁵,Wen Zhong¹²³⁴⁵,Ni Hai-Liang⁶⁷⁸⁹

Affiliation:

1. Antibiotics Research and Re-evaluation Key Laboratory of Sichuan Province

2. Sichuan Industrial Institute of Antibiotics

3. School of Pharmacy

4. Chengdu University

5. Chengdu 610016

6. College of Chemistry and Materials Science

7. Sichuan Normal University

8. Chengdu 610066

9. P. R. China

Abstract

We report a dearomative C3-phosphorylation and a tandem C3-phosphorylation/aromatization of 2-benzofuryl-ols with P(O)–H species to afford C3-phosphinoyl hydrobenzofurans and benzofurans, respectively.

Funder

National Natural Science Foundation of China

Chengdu University

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/QO/D1QO00076D

Reference91 articles.

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