Engineering plastic phase transitions <i>via</i> solid solutions: the case of “reordering frustration” in ionic plastic crystals of hydroxyquinuclidinium salts-Reference-Cited by-同舟云学术

Engineering plastic phase transitions via solid solutions: the case of “reordering frustration” in ionic plastic crystals of hydroxyquinuclidinium salts

Published:2022 Issue:8 Volume:7 Page:950-962
ISSN:2058-9689
Container-title:Molecular Systems Design & Engineering
language:en
Short-container-title:Mol. Syst. Des. Eng.

Author:

Ocak Samet¹,Birolo Rebecca²,Carì Gianluca¹,Bordignon Simone²,Chierotti Michele R.²^ORCID,Braga Dario¹^ORCID,Gobetto Roberto²^ORCID,Salzillo Tommaso³⁴^ORCID,Venuti Elisabetta³^ORCID,Yaffe Omer⁴^ORCID,d'Agostino Simone¹^ORCID

Affiliation:

1. Department of Chemistry “Giacomo Ciamician”, The University of Bologna, Via F. Selmi, 2, 40126 Bologna, Italy

2. Department of Chemistry and NIS Centre, The University of Turin, Via P. Giuria 7, 10125 Torino, Italy

3. Department of Industrial Chemistry “Toso Montanari”, The University of Bologna, Viale del Risorgimento 4, 40124, Bologna, Italy

4. Department of Chemical and Biological Physics, Weizmann Institute of Science, Rehovot 76100, Israel

Abstract

Reordering Frustration! Size and shape of the anions have been found to affect the order–disorder phase transition behavior in solid solutions-of ionic plastic crystals drastically. As a result, permanent plastic phases are obtained.

Funder

Università di Bologna

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Industrial and Manufacturing Engineering,Process Chemistry and Technology,Energy Engineering and Power Technology,Biomedical Engineering,Chemical Engineering (miscellaneous),Chemistry (miscellaneous)

Link

http://pubs.rsc.org/en/content/articlepdf/2022/ME/D2ME00040G

Reference85 articles.

1. Harnessing molecular rotations in plastic crystals: a holistic view for crystal engineering of adaptive soft materials

2. Plastic crystals: A historical review

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