Second-sphere effects on H2O2 activation by non-heme FeII complexes: role of a phenol group in the [H2O2]-dependent accumulation of FeIVO vs. FeIIIOOH-Reference-Cited by-同舟云学术

Second-sphere effects on H2O2 activation by non-heme FeII complexes: role of a phenol group in the [H2O2]-dependent accumulation of FeIVO vs. FeIIIOOH

Published:2021 Issue:47 Volume:12 Page:15691-15699
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Rebilly Jean-Noël¹,Herrero Christian¹,Sénéchal-David Katell¹,Guillot Régis¹^ORCID,Inceoglu Tanya¹,Maisonneuve Hélène¹,Banse Frédéric¹^ORCID

Affiliation:

1. Université Paris-Saclay, CNRS, Institut de Chimie Moléculaire et des Matériaux d'Orsay (ICMMO), 91405 Orsay Cedex, France

Abstract

A new FeII complex with a phenol group attached as a second coordination sphere moiety activates H2O2 to yield FeIVO following a mechanism reminiscent of peroxidase enzymes.

Funder

Agence Nationale de la Recherche

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/SC/D1SC03303D

Reference50 articles.

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