Investigation of the activation mode of vinylarene in Giri's Ni-catalyzed vinylarene intermolecular 1,2-alkylarylation cross-coupling: a theoretical study-Reference-Cited by-同舟云学术

Investigation of the activation mode of vinylarene in Giri's Ni-catalyzed vinylarene intermolecular 1,2-alkylarylation cross-coupling: a theoretical study

Published:2023 Issue:17 Volume:10 Page:4359-4367
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Liu Song¹²³^ORCID,Zhang Dianmin¹,Zhang Xiaoqing¹,Cheng Yuyan¹,Deng Hong¹

Affiliation:

1. Chongqing Key Laboratory of Environmental Materials and Remediation Technologies, College of Chemistry and Environmental Engineering, Chongqing University of Arts and Sciences, Chongqing, 402160, P. R. China

2. School of Chemistry and Chemical Engineering, Chongqing University, Chongqing 400030, China

3. Chongqing Precision Medical Industry Technology Research Institute, Chongqing 400084, P. R. China

Abstract

Computational evidence that supports a migratory insertion activation mode of alkenes in the Ni-catalyzed vinylarene 1,2-alkylarylation cross-coupling is presented. However, the activation mode of vinylarene was radical addition, when bipyridyl was used as a ligand.

Funder

Chongqing Basic and Frontier Research Project

Chongqing University of Arts and Science

Chongqing Municipal Education Commission

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/QO/D3QO00851G

Reference50 articles.

1. Strategies toward Dicarbofunctionalization of Unactivated Olefins by Combined Heck Carbometalation and Cross-Coupling

2. Developments in Photoredox/Nickel Dual-Catalyzed 1,2-Difunctionalizations

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