TBAI-catalyzed selective synthesis of sulfonamides and β-aryl sulfonyl enamines: coupling of arenesulfonyl chlorides and sodium sulfinates with tert-amines-Reference-Cited by-同舟云学术

TBAI-catalyzed selective synthesis of sulfonamides and β-aryl sulfonyl enamines: coupling of arenesulfonyl chlorides and sodium sulfinates with tert-amines

Published:2019 Issue:10 Volume:17 Page:2715-2720
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Jiang Hongmei¹²³⁴⁵,Tang Xiaoyue¹²³⁴,Xu Zhihui⁵⁶⁷⁸⁹,Wang Huixian¹²³⁴,Han Kang¹²³⁴,Yang Xiaolan¹²³⁴,Zhou Yuanyuan¹²³⁴,Feng Yong-Lai¹²³⁴,Yu Xian-Yong¹⁰¹¹¹²¹³,Gui Qingwen¹²³⁴⁵^ORCID

Affiliation:

1. College of Science

2. Hunan Agricultural University

3. Changsha 410128

4. People's Republic of China

5. State Key Laboratory of Chemo/Biosensing and Chemometrics

6. College of Chemistry and Chemical Engineering

7. Hunan University

8. Changsha 410082

9. P. R. China

10. Key Laboratory of Theoretical Organic Chemistry and Functional Molecule of Ministry of Education

11. Hunan University of Science and Technology

12. Xiangtan 411201

13. China

Abstract

A simple, practical and metal-free method for the synthesis of title compounds via the selective cleavage of C–N and C–H bonds through the iodine-catalyzed oxidation of arenesulfonyl chlorides and sodium sulfinates with tert-amines.

Funder

National Natural Science Foundation of China

Ministry of Agriculture of the People's Republic of China

Hunan Provincial Science and Technology Department

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/OB/C8OB02992J

Reference98 articles.

1. Carbon−Heteroatom Bond-Forming Reductive Eliminations of Amines, Ethers, and Sulfides