Ring-opening homo- and co-polymerization of lactides and ε-caprolactone by salalen aluminum complexes
Author:
Affiliation:
1. Dipartimento di Chimica e Biologia
2. Università di Salerno
3. 84084 Fisciano
4. Italy
5. School of Chemistry
6. Tel Aviv University
7. Tel Aviv 69978
8. Israel
9. Dipartimento di Scienze e Tecnologie
10. Università del Sannio
11. 82100 Benevento
Abstract
Salalen aluminum complexes gave isotactic polylactides from rac-LA, heterotactic polylactides from meso-LA and random copolymers of LA/CL. An experiment was designed to prove polymeryl exchange events.
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2015/DT/C4DT02616K
Reference48 articles.
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3. Metal catalysts for ε-caprolactone polymerisation
4. Stereoselective ring-opening polymerization ofrac-lactide with a single-site, racemic aluminum alkoxide catalyst: Synthesis of stereoblock poly(lactic acid)
5. Stereochemistry of Lactide Polymerization with Chiral Catalysts: New Opportunities for Stereocontrol Using Polymer Exchange Mechanisms
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