Hydrogen and oxygen activation by an iridium precursor containing the 4,5-bis(diphenylthiophosphinoyl)-1,2,3-triazolate ligand-Reference-Cited by-同舟云学术

Hydrogen and oxygen activation by an iridium precursor containing the 4,5-bis(diphenylthiophosphinoyl)-1,2,3-triazolate ligand

Published:2015 Issue:71 Volume:5 Page:58046-58054
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Hernández-Juárez M.¹²³⁴⁵,Toscano R. A.¹²³⁴⁵,Cortés-Guzmán F.¹²³⁴⁵,Zúñiga-Villarreal N.¹²³⁴⁵

Affiliation:

1. Instituto de Química

2. Universidad Nacional Autónoma de México

3. Ciudad Universitaria

4. D. F.

5. 04510 Mexico

Abstract

Complex [Ir(κ²-S,N-(4,5-(P(S)Ph₂)₂Tz))(coe)₂] (coe = cyclooctene) was prepared upon reaction of potassium 4,5-bis(diphenylthiophosphinoyl)-1,2,3-triazolate with [Ir(coe)₂(μ-Cl)]₂. Its phosphorus derivatives were susceptible of oxidative addition processes.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/RA/C5RA07698F

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