R/X exchange reactions in cis-[M(R)2{P(X)(NMeCH2)2}2] (M = Pd, Pt), via a phosphenium intermediate
Author:
Affiliation:
1. Department of Chemistry
2. Graduate School of Science
3. Osaka City University
4. Osaka 558-8585
5. Japan
6. Department of Chemistry and Biochemistry
7. Graduate School of Humanities and Sciences
8. Ochanomizu University
9. Tokyo 112-8610
Abstract
R/X exchange reactions in cis-[M(R)2{P(X)(NMeCH2)2}2] (M = Pd, Pt; R = aryl, alkyl; X = Cl, Br) were achieved for the first time to give cis-[M(X)2{P(R)(NMeCH2)2}2]. DFT calculations suggested that the exchange reaction proceeds via a phosphenium intermediate.
Funder
Japan Society for the Promotion of Science
Ministry of Education, Culture, Sports, Science, and Technology
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2016/DT/C6DT02314B
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4. The Development of Versatile Methods for Palladium-Catalyzed Coupling Reactions of Aryl Electrophiles through the Use of P(t-Bu)3 and PCy3 as Ligands
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