The doubly-bonded ditungsten anion [W2Cp2(μ-PPh2)(NO)2]−: an entry to the chemistry of unsaturated nitrosyl complexes-Reference-Cited by-同舟云学术

The doubly-bonded ditungsten anion [W2Cp2(μ-PPh2)(NO)2]−: an entry to the chemistry of unsaturated nitrosyl complexes

Published:2016 Issue:34 Volume:45 Page:13300-13303
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Alvarez M. Angeles¹²³⁴,García M. Esther¹²³⁴,García-Vivó Daniel¹²³⁴^ORCID,Ruiz Miguel A.¹²³⁴,Toyos Adrián¹²³⁴

Affiliation:

1. Departamento de Química Orgánica e Inorgánica/IUQOEM

2. Universidad de Oviedo

3. E-33071 Oviedo

4. Spain

Abstract

The title complex, the first anionic nitrosyl complex featuring a metal-metal double bond, displays substantial nucleophilicity, thus providing synthetic access to different unsaturated hydride and heterometallic derivatives, as well as a variety of electron-precise molecules.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C6DT02319C

Reference34 articles.

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2. Nitrosyl Complexes in Inorganic Chemistry, Biochemistry and Medicine, Structure and Bonding, ed. D. M. P. Mingos, 2014, vol. 153 and 154

3. Heme-Nitrosyls: Electronic Structure Implications for Function in Biology

4. Dinitrosyl Iron Complexes (DNICs): From Biomimetic Synthesis and Spectroscopic Characterization toward Unveiling the Biological and Catalytic Roles of DNICs

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