Cyclopentadienyl nickel(ii) N,C-chelating benzothiazolyl NHC complexes: synthesis, characterization and application in catalytic C–C bond formation reactions
Author:
Affiliation:
1. Department of Chemistry
2. National University of Singapore
3. Singapore 117543
4. Singapore
5. Institute of Materials Research and Engineering
6. Agency for Science
7. Technology and Research
8. Singapore 138634
Abstract
CpNi(ii) N,C-chelating benzothiazolyl NHC complexes have been synthesized. They are efficient catalysts for the homo-coupling of benzyl bromide in the presence of MeMgCl at r.t. with good function group tolerance.
Funder
Science and Engineering Research Council, Agency for Science, Technology and Research
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2016/DT/C6DT00252H
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