Unexpected synthesis of an Au2In2 tetrametallatricyclic complex from α-aminophosphines and formation of Au–In–P and Ag–In

Unexpected synthesis of an Au2In2 tetrametallatricyclic complex from α-aminophosphines and formation of Au–In–P and Ag–In–P nanomaterials

Published:2015 Issue:37 Volume:44 Page:16242-16246
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Chen Hsiao Wei¹²³⁴,Andy Hor T. S.¹²³⁴⁵,Pattacini Roberto⁶⁷⁸⁹¹⁰,Braunstein Pierre⁶⁷⁸⁹¹⁰

Affiliation:

1. Department of Chemistry

2. National University of Singapore

3. Singapore 117543

4. Singapore

5. Institute of Materials Research and Engineering

6. Laboratoire de Chimie de Coordination

7. Université de Strasbourg (UMR 7177 CNRS)

8. Institut Le Bel

9. Strasbourg

10. France

Abstract

Four Au–(μ-phosphinite)–In units form an unprecedented Au₂In₂ 12-membered metallacycle which intersects at the In centres an 8-membered ring containing two In–μ-phosphinate linkages, resulting in a tricyclic structure.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT02457A

Reference45 articles.

1. Mixed Phosphine−Phosphine Oxide Ligands

2. Coordination Properties of Tris(2-carboxyethyl)phosphine, a Newly Introduced Thiol Reductant, and Its Oxide

3. Synthesis of Hemilabile Phosphine−Phosphine Oxide Ligands via the Highly Selective Pd-Catalyzed Mono-oxidation of Bidentate Phosphines: Scope, Limitations, and Mechanism

4. Tin(II) Polyoxometalate as an Efficient Catalyst for the Selective Oxidation of Sulfides to Sulfoxides

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