Comprehensive analysis of C–H⋯π(alkyne) interactions in the crystal packing of diastereomers of 1,2-di(7′-methoxynaphth-1′-yl)-3,6-di(4′′-n-propylphenylethynyl)benzene

Author:

Nakamura Minami1,Kashiwagi Yukiyasu2ORCID,Morisue Mitsuhiko1ORCID

Affiliation:

1. Faculty of Molecular Chemistry and Engineering, Kyoto Institute of Technology, Matsugasaki, Sakyo-ku, Kyoto 606-8585, Japan

2. Osaka Research Institute of Industrial Science and Technology, 1-6-50, Morinomiya, Joto-ku, Osaka 536-8553, Japan

Abstract

An exceptional example of multiple C–H⋯π(alkyne) contacts has been discovered in the crystal packing of the syn-diastereomeric conformer of 1,2-di(7′-methoxynaphth-1′-yl)-3,6-di(4′′-n-propylphenylethynyl)benzene (syn-1).

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

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