Synthesis of colorless and high-refractive-index sulfoxide-containing polymers by the oxidation of poly(phenylene sulfide) derivatives

Author:

Watanabe Seigo1ORCID,Takayama Teru1,Nishio Hiromichi1,Matsushima Kanta1,Tanaka Yoko1,Saito Seiya1,Sun Yushun1,Oyaizu Kenichi1ORCID

Affiliation:

1. Department of Applied Chemistry and Research Institute for Science and Engineering, Waseda University, Tokyo, 169-8555, Japan

Abstract

A series of poly(phenylene sulfide) (PPS) derivatives can be bleached while maintaining high refractive indices, by partially incorporating sulfoxide bonds through their mCPBA oxidation, owing to the loss of lone pairs around the sulfide atoms.

Funder

Ministry of Education, Culture, Sports, Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

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