Palladium-catalyzed olefination of aryl/alkyl halides with trimethylsilyldiazomethane via carbene migratory insertion-Reference-Cited by-同舟云学术

Palladium-catalyzed olefination of aryl/alkyl halides with trimethylsilyldiazomethane via carbene migratory insertion

Published:2018 Issue:92 Volume:54 Page:12994-12997
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Mu Qiu-Chao¹²³⁴⁵,Wang Xing-Ben¹²³⁴,Ye Fei¹²³⁴,Sun Yu-Li¹²³⁴,Bai Xing-Feng¹²³⁴⁵,Chen Jing⁵⁶⁷⁴,Xia Chun-Gu⁵⁶⁷⁴,Xu Li-Wen¹²³⁴⁵^ORCID

Affiliation:

1. Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education

2. Hangzhou Normal University

3. Hangzhou 311121

4. P. R. China

5. State Key Laboratory for Oxo Synthesis and Selective Oxidation Lanzhou Institute of Chemical Physics

6. Chinese Academy of Sciences

7. and University of the Chinese Academy of Sciences

Abstract

One-pot formation of (E)-vinyl silanes and (E)-silyl-substituted α, β-unsaturated amides could be completed easily via palladium carbene migratory insertion in good yields and high chemoselectivity.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Jiangsu Province

Natural Science Foundation of Zhejiang Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2018/CC/C8CC07664B

Reference73 articles.

1. Transition-Metal-Catalyzed Cross-Couplings through Carbene Migratory Insertion

2. N-Tosylhydrazones: versatile synthons in the construction of cyclic compounds

3. Catalytic Cascade Reactions Involving Metal Carbene Migratory Insertion

4. Diazo Compounds and N-Tosylhydrazones: Novel Cross-Coupling Partners in Transition-Metal-Catalyzed Reactions

Cited by 9 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Stereoselective synthesis of monofluoroalkenyl silanes via copper-catalyzed decarboxylative silylation of α-fluoroacrylic acids;Tetrahedron;2023-06

2. Stereoselective Cyclopropanation of 1,1-Diborylalkenes via Palladium-Catalyzed (Trimethylsilyl)diazomethane Insertion;Organic Letters;2022-07-07

3. Asymmetric Hydrosilylation of β-Silyl Styrenes Catalyzed by a Chiral Palladium Complex;The Journal of Organic Chemistry;2022-01-26

4. Palladium-Catalyzed anti-Carbosilylation of Alkynes to Access Isoquinolinone-Containing Exocyclic Vinylsilanes;Organic Letters;2021-07-14

5. Synthesis of Functionalized Vinylsilanes via Metal-Free Dehydrogenative Silylation of Enamides;Organic Letters;2020-01-30