Copper(ii) and zinc(ii) complexation with N-ethylene hydroxycyclams and consequences on the macrocyclic backbone configuration

Author:

AlHaddad Nancy1ORCID,Lelong Evan1,Suh Jong-Min2ORCID,Cordier Marie3ORCID,Lim Mi Hee2ORCID,Royal Guy4ORCID,Platas-Iglesias Carlos5ORCID,Bernard Hélène1ORCID,Tripier Raphaël1ORCID

Affiliation:

1. Univ. Brest, UMR CNRS 6521 CEMCA, 6 Avenue Victor le Gorgeu, 29238 Brest, France

2. Department of Chemistry, Korea Advanced Institute of Science and Technology (KAIST), Daejeon 34141, Republic of Korea

3. Univ. Rennes, CNRS, ISCR (Institut des Sciences Chimiques de Rennes) UMR 6226, F-35000 Rennes, France

4. Univ. Grenoble Alpes, Département de Chimie Moléculaire UMR CNRS 5250, 38000 Grenoble, France

5. Departamento de Química, Facultade de Ciencias & Centro de Investigaciones Científicas Avanzadas (CICA), Universidade da Coruña, 15071 A Coruña, Spain

Abstract

We report a series of four cyclams and cross-bridged cyclams, N-functionalized by one hydroxyethyl arm, which may incorporate additional methyl(s) group(s).

Funder

Ministère de l'Education Nationale, de l'Enseignement Superieur et de la Recherche

Centre National de la Recherche Scientifique

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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