Rhodium-catalyzed arylative cyclization of alkynyl malonates by 1,4-rhodium(i) migration-Reference-Cited by-同舟云学术

Rhodium-catalyzed arylative cyclization of alkynyl malonates by 1,4-rhodium(i) migration

Published:2019 Issue:76 Volume:55 Page:11366-11369
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

O’Brien Luke¹²³⁴⁵,Karad Somnath Narayan¹²³⁴⁵,Lewis William⁶²⁴⁵^ORCID,Lam Hon Wai¹²³⁴⁵^ORCID

Affiliation:

1. The GlaxoSmithKline Carbon Neutral Laboratories for Sustainable Chemistry

2. University of Nottingham

3. Jubilee Campus

4. Nottingham

5. UK

6. School of Chemistry

Abstract

The synthesis of functionalized 1-tetralones by the rhodium(i)-catalyzed reaction of alkynyl malonates with arylboronic acids is described.

Funder

University of Nottingham

Engineering and Physical Sciences Research Council

H2020 Marie Skłodowska-Curie Actions

GlaxoSmithKline

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CC/C9CC05205D

Reference76 articles.

1. Catalytic Asymmetric Arylative Cyclization of Alkynals: Phosphine-Free Rhodium/Diene Complexes as Efficient Catalysts

2. Rhodium-Catalyzed Cyclization of 1,6-Enynes Triggered by Addition of Arylboronic Acids

3. Highly Chemo- and Enantioselective Arylative Cyclization of Alkyne-Tethered Electron-Deficient Olefins Catalyzed by Rhodium Complexes with Chiral Dienes

4. Cationic Pd(II)-Catalyzed Enantioselective Cyclization of Aroylmethyl 2-Alkynoates Initiated by Carbopalladation of Alkynes with Arylboronic Acids

5. Control of Chemoselectivity by Counteranions of Cationic Palladium Complexes: A Convenient Enantioselective Synthesis of Dihydrocoumarins

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