Construction of an all-substituted pyrrolidine derivative with multiple stereogenic centers and Betti-base-derived γ-amino alcohols by [1,2]-Wittig rearrangement-Reference-Cited by-同舟云学术

Construction of an all-substituted pyrrolidine derivative with multiple stereogenic centers and Betti-base-derived γ-amino alcohols by [1,2]-Wittig rearrangement

Published:2015 Issue:69 Volume:5 Page:55819-55824
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Wang Cai-Yun¹²³⁴,Dong Cheng¹²³⁴,Zheng Zhan-Jiang¹²³⁴,Xu Zheng¹²³⁴,Yang Ke-Fang¹²³⁴,Xu Li-Wen¹²³⁴⁵

Affiliation:

1. Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education (MOE)

2. Hangzhou Normal University

3. Hangzhou 311121

4. P. R. China

5. State Key Laboratory for Oxo Synthesis and Selective Oxidation

Abstract

The construction of Betti base-derived γ-amino alcohols and all-substituted pyrrolidine derivative with multiple stereogenic centers has been developed successfully through neighboring lithium-assisted [1,2]-Wittig rearrangement (NLAWR).

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/RA/C5RA09145D

Reference63 articles.

1. [2,3]-Wittig sigmatropic rearrangements in organic synthesis

2. [1,2]-Wittig Rearrangement of Acetal Systems: A Highly Stereocontrolled Conversion of O-Glycosides to C-Glycosides

3. Stereospecificity of the 1,2-Wittig Rearrangement: How Chelation Effects Influence Stereochemical Outcome

4. Wittig rearrangement of allyl and propargyl furfuryl ethers leading to 2-furylmethanol derivatives

5. Stereoselective Synthesis of Highly FunctionalizedC-Glycosides based on Acetal [1,2] and [1,4] Wittig Rearrangements

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